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Paperback The Chemistry of Zirconacycles and 2,6-Diazasemibullvalenes: Synthesis, Structures, Reactions, and Applications in the Synthesis of Novel N-Heterocycl Book

ISBN: 3662515148

ISBN13: 9783662515143

The Chemistry of Zirconacycles and 2,6-Diazasemibullvalenes: Synthesis, Structures, Reactions, and Applications in the Synthesis of Novel N-Heterocycl

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Book Overview

Introduction to Zirconacycle Chemistry.- Zirconocene-Mediated Cyclization of Bis(alkynyl)silanes and Nitriles: Synthesis of N-Heterocycles and Isolation, Characterization and Synthetic Application of Zr/Si-containing Reactive Intermediates.- Bulky-Nitrile Coordination Induced Skeleton Rearrangement of Zr/Si-containing Metallacycles and Selective Synthesis of 5-Azaindoles.- Introduction to Semibullvalenes and Azasemibullvalenes.- Diazasemibullvalenes: Synthesis, Structure, Theoretical Analysis and Computational Chemistry.- Diazasemibullvalenes: Reaction Chemistry and Synthetic Application.

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